Boiler Water treatment

Boiler water dosing guide – Aided with simulators

boiler water dosing guide
Boiler Water Chemistry: Master Dashboard

Boiler water dosing guide by Dieselship Academy

Master Dashboard: From daily operational checks to advanced troubleshooting and chemical concepts.

Daily Routine: The Traffic Light System

Operational Logic: Test Blowdown Dose

Pre-Req: Flush sample line for 3-5 mins

Step 1: Input Test Results

TDS (Conductivity)
Phosphate Reserve
P-Alkalinity
Chloride
M-Alk Spike

Step 2: Blowdown (Yellow Light)

Maintain routine Surface (Scum) Blowdown. Perform short Bottom Blowdown to clear sludge.

Step 3: Dosing (Green Light)

Apply standard daily chemical dosage.

Reason: Replace chemicals lost during Step 2. Restore reserves.

1. Alkalinity: The "P" vs. "M" Battle

Alkalinity neutralizes acid to prevent corrosion (Target pH 9.5–11). However, we must balance "Active" protection against the risk of caustic embrittlement. Use the simulator below to understand the relationship between P-Alkalinity (Primary Control) and M-Alkalinity (Total/Contamination Monitor).

Lab Simulator Controls

Target: 100–300 ppm. Measures OH⁻ & ½ CO₃²⁻.

Measures All OH⁻, CO₃²⁻ & HCO₃⁻.

Rule of Thumb

In a healthy boiler,
2 x P-Alkalinity ≈ M-Alkalinity.

System Status: Assessing...

Adjust sliders to simulate water conditions.

2. Oxygen Scavengers: The "Pit Fighter"

Dissolved Oxygen causes Pitting Corrosion[Image of oxygen pitting corrosion]—pinhole drills that destroy tubes in weeks. We add scavengers to "hunt" oxygen. Select a chemical type and adjust the reserve level to see the consequences.

Hydrazine ($N_2H_4$)

  • Pro: Adds NO solids (TDS). Promotes magnetite layer.
  • Con: Carcinogenic and toxic. Requires strict handling.

Simulate Test Result: Scavenger Reserve (ppm)

0 ppm 0.5 ppm 2.0 ppm
Result: 0.5 ppm SAFE ZONE

Guards are waiting. Oxygen is dead.

Critical Warning: If Red Iron Oxide (Rust) is found in the boiler, oxygen attack is active regardless of reserve. Investigate feed system tightness immediately.

3. Phosphate Hideout: The "Ghost" Effect

Phosphate becomes less soluble at high temperatures (High Load) and plates onto tubes, disappearing from the water test. When load drops, it returns. Don't panic dose! Use the controls to simulate load changes and observe the "Ghost" effect.

Current State Steady Load

The Mistake

Engineer sees 0 ppm at High Load and panic doses. When load drops, hidden phosphate returns + new dose = Massive Spike (>80ppm).

Correct Action

If P drops at High Load: Do NOT Dose. Wait/Reduce load for 1 hr to confirm hideout. Only dose if P stays low at Low Load.

4. Condensate pH: The "Silent Killer"

Steam absorbs CO₂ to form Carbonic Acid, eating copper pipes. Volatile amines in your boiler treatment travel with steam to neutralize this. Click the nodes in the system loop to trace the path and check the pH risks.

Boiler

Amines Added

Steam Line

Amines Travel

Condenser

Acid Forms

Hotwell

TEST POINT

Hotwell Analysis (The Test)

This is where we verify if the amines neutralized the Carbonic Acid. Use the buttons below to diagnose the pH reading.

Condition: Safe Zone

Amines are effectively neutralizing acid. Corrosion is minimized.

© 2025 Dieselship Academy. All rights reserved.

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About Ram Govindasamy

Ram Govindasamy is a seasoned marine chief engineer with specialized expertise in operating and managing large cruise ships, both in shipboard and shore-based roles. Leveraging his extensive experience, Ram founded Dieselship, a company dedicated to serving the maritime community through diverse offerings. Dieselship provides academic resources, develops innovative maritime software to streamline shipboard and shore-based operations, and supplies ship provisions and spare parts. A passionate computer enthusiast, Ram enjoys creating web-based applications, designing websites, and programming solutions. He is an active contributor to the maritime industry, authoring technical articles and producing educational videos for Dieselship and various other maritime platforms. Ram has a keen interest in Maritime Law and Technical Operations, and he thrives on collaborating with like-minded professionals. He is particularly enthusiastic about creating web-based platforms, asset maintenance and inventory management programs, and planned maintenance systems, fostering innovation and efficiency in the maritime sector.

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